Carbon-Carbon Bond Formation via Palladium-Catalyzed Reductive Coupling of Aryl Halides in Air and Water

2002 ◽  
Vol 344 (3-4) ◽  
pp. 399-405 ◽  
Author(s):  
Sripathy Venkatraman ◽  
Taisheng Huang ◽  
Chao-Jun Li
Keyword(s):  
Bond Formation ◽  
Aryl Halides ◽  
Reductive Coupling ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Palladium Catalyzed

Palladium chloride catalyzed photochemical Heck reaction

2013 ◽  
Vol 91 (5) ◽  
pp. 348-351 ◽  
Author(s):  
Suresh B. Waghmode ◽  
Sudhir S. Arbuj ◽  
Bina N. Wani ◽  
C.S. Gopinath
Keyword(s):  
Visible Light ◽  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Aryl Halides ◽  
Palladium Chloride ◽  
Carbon Bond ◽  
Excellent Yield ◽  
Carbon Carbon Bond ◽  
Uv Visible

PdCl2 catalyzed carbon–carbon bond formation (Heck reaction) between substituted aryl halides and olefins was carried out without a ligand, under irradiation with UV–visible light. The results demonstrated that UV–visible light accelerated the rate of the reaction, leading to an excellent yield of corresponding products. The recovered palladium nanoparticles could be thermally recycled several times. PdCl2 gave excellent conversion up to the fifth addition of substrate.

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